[2.2]Paracyclophane-bridged platinum(ii) complexes for silver(i) recognition with emission enhancement. Issue 90 (28th October 2021)

• Record Type: Journal Article
• Authors: Tian, Yukui; Chen, Bin; Jiang, Sixun; Yuan, Ming; Ren, Jie; Wang, Feng
• Is Part Of: Chemical communications. Volume 57:Issue 90(2021)
• Page Start: 11996
• Page End: 11999
• Publication Date: 2021-10-28
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/d1cc04806f
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : A [2.2]paracyclophane-bridged bimetallic alkynylplatinum(ii ) terpyridyl complex displays severe emission quenching due to the presence of intramolecular π–π interactions. Abstract : A [2.2]paracyclophane-bridged bimetallic alkynylplatinum(ii ) terpyridyl complex displays severe emission quenching due to the presence of intramolecular π–π interactions. It undergoes an adaptive conformational change upon recognizing Ag +, which attenuates the intramolecular stacking strength and thereby exhibits "turn-on" emission character.