[2.2]Paracyclophane-bridged platinum(ii) complexes for silver(i) recognition with emission enhancement. Issue 90 (28th October 2021) - Tian, Yukui
Abstract : A [2.2]paracyclophane-bridged bimetallic alkynylplatinum(ii ) terpyridyl complex displays severe emission quenching due to the presence of intramolecular π–π interactions. Abstract : A [2.2]paracyclophane-bridged bimetallic alkynylplatinum(ii ) terpyridyl complex displays severe emission quenching due to the presence of intramolecular π–π interactions. It undergoes an adaptive conformational change upon recognizing Ag +, which attenuates the intramolecular stacking strength and thereby exhibits "turn-on" emission character.