A new sensor for the rapid electrochemical detection of ractopamine in meats with high sensitivity. (30th March 2023)

• Record Type: Journal Article
• Authors: Li, Kenken; Cui, Jiarui; Yang, Qi; Wang, Songlei; Luo, Ruiming; Rodas-Gonzalez, Argenis; Wei, Peiyuan; Liu, Li
• Is Part Of: Food chemistry. Volume 405:Part A(2023)
• Publication Date: 2023-03-30
• Subjects: Ractopamine -- Graphitic carbon nitrides -- Copper-cobalt alloy nanoparticles -- Electrochemical sensor -- Detection; Food -- Analysis -- Periodicals; Food -- Composition -- Periodicals; 664
• DOI: 10.1016/j.foodchem.2022.134791
• Languages: English
• ISSNs: 0308-8146

Abstract

Highlights: A novel g-C3 N4 /Cu@CoO/NC compound was prepared for ractopamine detection. The sensor has a wide linear range and low detection limit (1.53 nmol/L). Pork, pork liver and lamb were selected as real samples. The determination of ractopamine in meats confirmed the potential of the method. Abstract: In this research, g-C3 N4 /Cu@CoO/NC, which contained graphitic phase carbon nitride (g-C3 N4 ) with a binary nanostructure and Cu@CoO/NC with a bimetallic MOF precursor, was constructed by a low-temperature pyrolysis process. The g-C3 N4 /Cu@CoO/NC was characterised by several techniques, including X-ray diffraction, scanning electron microscope, transmission electron microscope and X-ray photoelectron spectroscopy. Further, it was used to prepare an electrochemical sensor for the detection of ractopamine (RAC) in meat samples. The sensor showed excellent electrochemical oxidation characteristics for RAC detection, with a wide linear range (0.005 μmol/L to 32.73 μmol/L) and low detection limit (1.53 nmol/L). Meanwhile, the reproducibility, stability and interference of the g-C3 N4 /Cu@CoO/NC/GCE sensor were found to be excellent. Besides, the g-C3 N4 /Cu@CoO/NC/GCE sensor was well-used for the detection of RAC in pork, pig liver and lamb samples with recovery rates ranging from 96.5 % to 102.2 %.