Carbonyl hypoiodites from pivalic and trimesic acid and their silver(i) intermediates. Issue 38 (12th September 2022)

• Record Type: Journal Article
• Authors: Ward, Jas S.; Martõnova, Jevgenija; Wilson, Laura M. E.; Kramer, Eric; Aav, Riina; Rissanen, Kari
• Is Part Of: Dalton transactions. Volume 51:Issue 38(2022)
• Page Start: 14646
• Page End: 14653
• Publication Date: 2022-09-12
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/d2dt01988d
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : For the first time, tris (O–I–N) compounds were synthesised and characterised in both the solution (NMR) and solid states (SCXRD). Abstract : The first tris (O–I–N) carbonyl hypoiodites have been synthesised based on trimesic acid and pyridine or 4-methylpyridine, with their structures definitively confirmed by single crystal X-ray diffraction (SCXRD). The more soluble carbonyl hypoiodites based on pivalic acid have also been studied via NMR, SCXRD, and computational analyses, enabling the study of the direct silver(i ) precursor and intermediates of the resulting carbonyl hypoiodites generated using a range of substituted pyridines.