Carbonyl hypoiodites from pivalic and trimesic acid and their silver(i) intermediates. Issue 38 (12th September 2022) - Ward, Jas S.
Abstract : For the first time, tris (O–I–N) compounds were synthesised and characterised in both the solution (NMR) and solid states (SCXRD). Abstract : The first tris (O–I–N) carbonyl hypoiodites have been synthesised based on trimesic acid and pyridine or 4-methylpyridine, with their structures definitively confirmed by single crystal X-ray diffraction (SCXRD). The more soluble carbonyl hypoiodites based on pivalic acid have also been studied via NMR, SCXRD, and computational analyses, enabling the study of the direct silver(i ) precursor and intermediates of the resulting carbonyl hypoiodites generated using a range of substituted pyridines.