Analysis of the chemical composition of natural carbohydrates – An overview of methods. (15th November 2022)

• Record Type: Journal Article
• Authors: Kurzyna-Szklarek, Magdalena; Cybulska, Justyna; Zdunek, Artur
• Is Part Of: Food chemistry. Volume 394(2022)
• Publication Date: 2022-11-15
• Subjects: 1H NMR Proton Nuclear Magnetic Resonance -- 2D-NMR Two-Dimensional Nuclear Magnetic Resonance -- 13C NMR Carbon-13 (C13) Nuclear Magnetic Resonance -- AA Anthranilic Acid -- ACN Acetonitrile -- AOAC Association Of Official Analytical Chemists -- API Atmospheric Pressure Ionization -- C6D6 Deuterated Benzene -- CAD Corona Charged Aerosol Detector -- CDCL3 Deuterated Chloroform -- CE Capillary Electrophoresis -- D2O Deuterated Water -- DEAE Diethylaminoethyl -- DMSO-D6 Deuterated Dimethyl Sulfoxide -- DNS Method Dinitrosalicylic Acid Method -- EIMSC Extended I Multiplicative Scatter Correction -- ELSD Evaporative Light Scattering Detector -- EMSC Extended Multiplicative Scatter Correction -- ESI Electrospray Ionization -- F Furfural -- FD Fluorescence Detector -- FT-NIR Fourier Transform Near-Infrared -- FID Flame Ionization Detector -- GC Gas Chromatography -- HILIC Hydrophilic Interaction Liquid Chromatography -- HPAEC High Performance Anion-Exchange Chromatography -- HMF 5-Hydroxymethyl-2-Furaldehyde -- IEC Ion Exclusion Chromatography -- IMSC Inverse Multiplicative Scatter Correction -- IPLS Interval Partial Least Squares -- IR Infrared -- LC/MS Liquid Chromatography/Mass Spectrometry -- LEC Ligand Exchange Chromatography -- LLE Liquid-Liquid Extraction -- MALDI MS Matrix-Assisted Laser Desorption, Ionisation Mass Spectrometry -- MBTH Method 3-Methyl-2-Benzothiazoline Hydrazine Hydrochloride Method -- MIR Mid Infrared -- MS Mass Spectrometry -- MSC Multiplicative Scatter Correction -- NIR Near Infrared -- NMR Nuclear Magnetic Resonance -- NP – HPLC Normal Phase HPLC -- NPD Nitrogen Phosphorus Detector -- NW Norris-Williams -- PAHBAH Method Carbohydrate Determination With 4-Hydroxybenzoic Acid Hydrazide -- PAD Pulsed Amperometry Detector -- PCA Principle Component Analysis -- PLSR Partial Least Squares Regression -- PMP 1-Phenyl- 3-Methyl- 5pyrazolone -- PMPA 4-(3-Methyl-5-Oxo-2-Pyrazon-1-yl) Benzoic Acid -- PMPMP 1-(4-Methoxyphenyl)-3-Methyl-5-Pyrazolone -- PDA Detector Photodiode Array Detector -- RID Refractive Index Detector -- RP- HPLC Reversed Phase HPLC -- SDS Sodium Dodecyl Sulphate -- SG Savitzky-Golay -- SN Method Somogyi and Nelson's Method -- SNV Standard Normal Variate -- SPA Successive Projections Algorithm -- SPE Solid Phase Extraction -- SPME Solid Phase Microextraction -- TMS Ether Trimethylsilyl Ether -- TMSO Trimethylsilyl Oximes -- UHPLC Ultra-High Performance Liquid Chromatography -- UV/UV–Vis Ultraviolet /Ultraviolet–Visible -- UV Detector Ultraviolet Detector -- VIS Visible Spectrum; Monosaccharide composition -- Detection method -- Polysaccharide hydrolysis -- Chromatography -- Spectroscopy; Food -- Analysis -- Periodicals; Food -- Composition -- Periodicals; 664
• DOI: 10.1016/j.foodchem.2022.133466
• Languages: English
• ISSNs: 0308-8146

Abstract

Highlights: A variety of sample pre-treatment methods of biological sample were reviewed. Analytical methods for determination sugars in plant tissues were focused. Proposals for the procedure to identification and quantification the sugar content in the complex samples were presented. The pros and cons of each method were pointed out. Abstract: Natural carbohydrates are gaining importance over a wide spectrum of human activity due to their versatile functionalities. The properties of carbohydrates are currently used in many branches of industry and new possibilities of their utilization, like in medicine or materials science, are demonstrated systematically. The attractive properties of carbohydrates result from their chemical structure and ability to form macromolecules and derivatives. Each application of carbohydrate requires a knowledge of their chemical composition, which due to the number and differentiation of monosaccharides and their spatial forms is often challenging. This review presents an overview on sample preparation and the methods used for the determination of the fine chemical structure of natural carbohydrates. Most popular and reliable colorimetric, chromatographic and spectroscopic methods are presented with an emphasis on their pros and cons.