Preparation, suppressed the charge carriers recombination, and improved photocatalytic performance of g-C3N4/MoS2 p-n heterojunction photocatalyst for tetracycline and dyes degradation upon visible light. (15th June 2022)

• Record Type: Journal Article
• Authors: Cao, Yan; Alsharif, Sameer; El-Shafay, A.S.
• Is Part Of: Materials science in semiconductor processing. Volume 144(2022)
• Publication Date: 2022-06-15
• Subjects: G-C3N4/MoS2 -- p-n heterojunction -- Photocatalyst -- Tetracycline -- Dyes; Semiconductors -- Periodicals; Integrated circuits -- Materials -- Periodicals; Semiconducteurs -- Périodiques; Circuits intégrés -- Matériaux -- Périodiques; Electronic journals; 621.38152
• DOI: 10.1016/j.mssp.2022.106569
• Languages: English
• ISSNs: 1369-8001

Abstract

Abstract: Operative charge separation, visible spectrum absorption, and increase of active sites are considered as effective factors in improving the performance of photocatalysts in the design of photocatalytic systems. Among photocatalysts, graphite carbon nitride (g-C3 N4 ) has been used in various fields, but research is still ongoing to achieve superior photocatalysts based on g-C3 N4 . In this work, the vision was to enhance the photocatalytic accomplishment of g-C3 N4 through the construction of p-n heterojunction with MoS2 semiconductor. The physicochemical properties of the as-synthesized photocatalysts were evaluated by TEM, FESEM, HRTEM, EDX, mapping, FT-IR, XRD, BET, XPS, PL, UV–vis DRS, photocurrent, EIS, and Mott-Schottky. The prepared photocatalysts were employed under visible light to degradation of tetracycline (TC), and the g-C3 N4 /MoS2 nanocomposite achieved a rate constant of 547 × 10 −4 min −1, which was 12.7 and 17.4-folds higher than g-C3 N4 and MoS2, respectively. Degradation of rhodamine B (RhB) and methylene blue (MB) as dye contaminants also showed that the photocatalytic activity of the nanocomposite was improved relative to the constituents. The planar structure of g-C3 N4 and MoS2 gives a shorter path for the transfer of charge carriers to the surface, thus increasing the efficiency of the photocatalyst. Also, the different analysis and experimental tests showed that the improvement of visible spectrum absorption, high specific surface area, and p-n heterojunction construction led to increased production of active species and suppressed recombination of electron-hole pairs, thereby significantly ameliorating photocatalytic activity. The charge migration mechanism between g-C3 N4 and MoS2 was carefully investigated and discussed. The present work could offer new acumen into the synthesis and application of g-C3 N4 -based heterojunctions. Graphical abstract: Image 1 Highlights: A novel g-C3 N4 /MoS2 p-n heterojunction photocatalyst was prepared by hydrothermal method. Different properties of prepared samples were thoroughly analyzed. The photocatalytic activity was inquired by degradation of TC, RhB, and MB under visible light irradiation. Construction of p-n heterojunction significantly increased g-C3 N4 /MoS2 nanocomposite photocatalytic activity than counterparts.