One step thermolysis of Sb-Mercaptopropionic acid complex in ambient air atmosphere for growing Sb2S3 thin films with controlled microstructure. (January 2021)

• Record Type: Journal Article
• Authors: Sharma, Vikas; Ilaiyaraja, P.; Dakshinamurthy, Athrey C.; Sudakar, C.
• Is Part Of: Materials science in semiconductor processing. Volume 121(2021)
• Publication Date: 2021-01
• Subjects: Sb2S3 -- Drop casting -- Sb-MPA complex -- Photoconductivity; Semiconductors -- Periodicals; Integrated circuits -- Materials -- Periodicals; Semiconducteurs -- Périodiques; Circuits intégrés -- Matériaux -- Périodiques; Electronic journals; 621.38152
• DOI: 10.1016/j.mssp.2020.105330
• Languages: English
• ISSNs: 1369-8001

Abstract

Abstract: Synthesis of phase pure Sb2 S3 in open atmosphere has been a long-time challenging task due to the oxidation of metal. Here, we demonstrate a robust, one-step solution approach for synthesis of Sb2 S3 thin films in open air atmosphere. One-step thermolysis of Sb-MPA complex obtained by mixing antimony chloride and 3-Mercaptopropionic acid (3-MPA) in polar and non-polar solvents yields phase pure thin films. Upon changing the concentration of sulphur in the solvent and polarity of solvent, different microstructures of Sb2 S3 such as nanostripes, nanorods and tubular morphology evolve. Irrespective of sulphur concentration in the precursor solution, Sb2 S3 thin films are always phase pure and formed in stoichiometric composition. The films are photoconductive in nature and morphology of Sb2 S3 influences the photoconductivity. This novel and facile methodology will open new avenues for direct deposition of Sb2 S3 thin films for wide range of applications including optoelectronics, photovoltaics and photocatalysis research. Highlights: One step thermolysis under ambient air atmosphere is used to grow Sb2 S3 thin films. Stoichiometric Sb2 S3 with different microstructures are obtained by changing solvent. Sb:S ratio in the precursor influences microstructure, size and photoconductivity. Sb2 S3 exhibits higher photoconductivity when made with stoichiometric Sb:S ratio. Higher sulphur concentration in the solution decreases photoconductivity.