Modeling of the elementary gas‐phase reaction during chemical vapor deposition of silicon carbide from CH3SiCl3/H2. Issue 6 (23rd March 2020)

• Record Type: Journal Article
• Authors: Sato, Noboru; Funato, Yuichi; Fukushima, Yasuyuki; Momose, Takeshi; Koshi, Mitsuo; Shimogaki, Yukihiro
• Is Part Of: International journal of chemical kinetics. Volume 52:Issue 6(2020)
• Page Start: 359
• Page End: 367
• Publication Date: 2020-03-23
• Subjects: CH3SiCl3 -- chemical vapor deposition -- gas‐phase reaction -- kinetics -- silicon carbide; Chemical kinetics -- Periodicals; 541.394
• DOI: 10.1002/kin.21355
• Languages: English
• ISSNs: 0538-8066

Abstract

Abstract: We established a gas‐phase, elementary reaction model for chemical vapor deposition of silicon carbide from methyltrichlorosilane (MTS) and H2, based on the model developed at Iowa State University (ISU). The ISU model did not reproduce our experimental results, decomposition behavior of MTS in the gas phase in an environment with H2 . Therefore, we made several modifications to the ISU model. Of the reactions included in existing models, 236 were lacking in the ISU model, and thus were added to the model. In addition, we modified the rate constants of the unimolecular reactions and the recombination reactions, which were treated as a high‐pressure limit in the ISU model, into pressure‐dependent rate expressions based on the previous reports (to yield the ISU+ model), for example, H2 (+M) → H + H(+M), but decomposition behavior remained poorly reproducible. To incorporate the pressure dependencies of unimolecular decomposition rate constants, and to increase the accuracies of these constants, we recalculated the rate constants of five unimolecular decomposition reactions of MTS using the Rice‐Ramsperger‐Kassel‐Marcus method at the CBS‐QB3 level. These chemistries were added to the ISU+ model to yield the UT2014 model. The UT2014 model reproduced overall MTS decomposition. From the results of our model, we confirmed that MTS mainly decomposes into CH3 and SiCl3 at the temperature around 1000°C as reported in the several studies.