A zinc(ii) metal–organic framework with high affinity for CO2 based on triazole and tetrazolyl benzene carboxylic acid. Issue 24 (29th May 2019)

• Record Type: Journal Article
• Authors: Sheng, Donghai; Zhang, Ying; Han, Yang; Xu, Guang; Song, Qingxiang; Hu, Yanping; Liu, Xiangyun; Shan, Dongming; Cheng, Achao
• Is Part Of: CrystEngComm. Volume 21:Issue 24(2019)
• Page Start: 3679
• Page End: 3685
• Publication Date: 2019-05-29
• Subjects: Crystals -- Periodicals; Crystal growth -- Periodicals; Crystallography -- Periodicals; Cristaux -- Périodiques; Cristaux -- Croissance -- Périodiques; Cristallographie -- Périodiques; 548
• DOI: 10.1039/c9ce00513g
• Languages: English
• ISSNs: 1466-8033

Abstract

Abstract : A new metal–organic framework {[Zn2 (Htzba)2 (dmtrz)]·(CH3 )2 NH} n (1 ) has already been solvothermally synthesized that exhibits a high CO2 uptake capacity. Abstract : A new metal–organic framework {[Zn2 (Htzba)2 (dmtrz)]·(CH3 )2 NH} n (1 ) that has already been solvothermally synthesized exhibits a high CO2 uptake capacity based on experimental and simulation calculation results. Furthermore, the selectivities to CO2 /CH4 and CO2 /N2 are predicted by IAST to be 41.19 and 46.21 at 298 K and 100 kPa, respectively. The superior performance suggests that1 is a promising candidate for CO2 separation.