A zinc(ii) metal–organic framework with high affinity for CO2 based on triazole and tetrazolyl benzene carboxylic acid. Issue 24 (29th May 2019) - Sheng, Donghai
Abstract : A new metal–organic framework {[Zn2 (Htzba)2 (dmtrz)]·(CH3 )2 NH} n (1 ) has already been solvothermally synthesized that exhibits a high CO2 uptake capacity. Abstract : A new metal–organic framework {[Zn2 (Htzba)2 (dmtrz)]·(CH3 )2 NH} n (1 ) that has already been solvothermally synthesized exhibits a high CO2 uptake capacity based on experimental and simulation calculation results. Furthermore, the selectivities to CO2 /CH4 and CO2 /N2 are predicted by IAST to be 41.19 and 46.21 at 298 K and 100 kPa, respectively. The superior performance suggests that1 is a promising candidate for CO2 separation.