Palladium NPs supported on sulfonic acid functionalized metal–organic frameworks as catalysts for biomass cascade reactions. Issue 17 (4th April 2019)

• Record Type: Journal Article
• Authors: Zhang, Xibo; Chen, Luning; Li, Yongjian; Li, Huiqi; Xie, Zhaoxiong; Kuang, Qin; Zheng, Lansun
• Is Part Of: Dalton transactions. Volume 48:Issue 17(2019)
• Page Start: 5515
• Page End: 5519
• Publication Date: 2019-04-04
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c9dt00348g
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : Pd nanoparticles supported on –SO3 H functionalized MIL-101 matrices were designed and synthesized as hydrogenation/esterification multifunctional catalysts for biomass cascade reactions. Abstract : Highly distributed Pd NPs supported on the surface of sulfonic acid functionalized metal organic frameworks (MIL-101-SO3 H) were synthesized via a simple thermal decomposition method. The as-synthesized Pd/MIL-101-SO3 H was used to catalyze a hydrogenation/esterification cascade reaction for the conversion of biomass derivatives (furoic acid) into high value chemicals (ethyl tetrahydro-2-furoate).