Palladium NPs supported on sulfonic acid functionalized metal–organic frameworks as catalysts for biomass cascade reactions. Issue 17 (4th April 2019) - Zhang, Xibo
Abstract : Pd nanoparticles supported on –SO3 H functionalized MIL-101 matrices were designed and synthesized as hydrogenation/esterification multifunctional catalysts for biomass cascade reactions. Abstract : Highly distributed Pd NPs supported on the surface of sulfonic acid functionalized metal organic frameworks (MIL-101-SO3 H) were synthesized via a simple thermal decomposition method. The as-synthesized Pd/MIL-101-SO3 H was used to catalyze a hydrogenation/esterification cascade reaction for the conversion of biomass derivatives (furoic acid) into high value chemicals (ethyl tetrahydro-2-furoate).