Alkylative kinetic resolution of vicinal diols under phase-transfer conditions: a chiral ammonium borinate catalysis. Issue 5 (19th December 2017)
- Record Type:
- Journal Article
- Title:
- Alkylative kinetic resolution of vicinal diols under phase-transfer conditions: a chiral ammonium borinate catalysis. Issue 5 (19th December 2017)
- Main Title:
- Alkylative kinetic resolution of vicinal diols under phase-transfer conditions: a chiral ammonium borinate catalysis
- Authors:
- Pawliczek, Martin
Hashimoto, Takuya
Maruoka, Keiji - Abstract:
- Abstract : Alkylative kinetic resolution of vicinal alcohols is realized by a cooperative chiral ammonium borinate catalysis. Abstract : Herein, we report the first alkylative kinetic resolution of vicinal alcohols realized by cooperative use of a chiral quaternary ammonium salt and an achiral borinic acid. In addition, a catalytic regioselective alkylation of a secondary alcohol in the presence of an unprotected primary one is presented, emphasizing the unique selectivity and potential of this ammonium borinate catalysis.
- Is Part Of:
- Chemical science. Volume 9:Issue 5(2018)
- Journal:
- Chemical science
- Issue:
- Volume 9:Issue 5(2018)
- Issue Display:
- Volume 9, Issue 5 (2018)
- Year:
- 2018
- Volume:
- 9
- Issue:
- 5
- Issue Sort Value:
- 2018-0009-0005-0000
- Page Start:
- 1231
- Page End:
- 1235
- Publication Date:
- 2017-12-19
- Subjects:
- Chemistry -- Periodicals
540.5 - Journal URLs:
- http://pubs.rsc.org/en/Journals/JournalIssues/SC ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c7sc04854h ↗
- Languages:
- English
- ISSNs:
- 2041-6520
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3151.490000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 5789.xml