Polyoxovanadate-based organic–inorganic hybrids: from {V5O9Cl} clusters to nanosized octahedral cages. Issue 9 (4th February 2016)

• Record Type: Journal Article
• Authors: Zhang, Yu-Teng; Wang, Xin-Long; Zhou, En-Long; Wu, Xue-Song; Song, Bai-Qiao; Shao, Kui-Zhan; Su, Zhong-Min
• Is Part Of: Dalton transactions. Volume 45:Issue 9(2016)
• Page Start: 3698
• Page End: 3701
• Publication Date: 2016-02-04
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c5dt04764a
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : Three nanosized polyoxovanadate-based metal–organic polyhedra have been successfully synthesized, which adopt isostructural octahedral cage geometries. Abstract : Three polyoxovanadate-based metal–organic polyhedra (denoted asVMOP-1, -2, and-3 ), adopting isostructural discrete octahedral cage geometries, were successfully synthesized under solvothermal conditions. These structures are all built up from the same pentavanadate {V5 O9 Cl} cluster connected by linear bidentate ligands (H2 L1 = H2 BDC, H2 L2 = H2 BDC-NH2, H2 L3 = H2 BDC-Br), respectively.