Polyoxovanadate-based organic–inorganic hybrids: from {V5O9Cl} clusters to nanosized octahedral cages. Issue 9 (4th February 2016) - Zhang, Yu-Teng
Abstract : Three nanosized polyoxovanadate-based metal–organic polyhedra have been successfully synthesized, which adopt isostructural octahedral cage geometries. Abstract : Three polyoxovanadate-based metal–organic polyhedra (denoted asVMOP-1, -2, and-3 ), adopting isostructural discrete octahedral cage geometries, were successfully synthesized under solvothermal conditions. These structures are all built up from the same pentavanadate {V5 O9 Cl} cluster connected by linear bidentate ligands (H2 L1 = H2 BDC, H2 L2 = H2 BDC-NH2, H2 L3 = H2 BDC-Br), respectively.