Bifunctional AgOAc/ThioClickFerrophos catalyzed asymmetric 1, 3-dipolar cycloaddition reaction of azomethine ylides to nitroalkenes. Issue 21 (26th May 2016)
- Record Type:
- Journal Article
- Title:
- Bifunctional AgOAc/ThioClickFerrophos catalyzed asymmetric 1, 3-dipolar cycloaddition reaction of azomethine ylides to nitroalkenes. Issue 21 (26th May 2016)
- Main Title:
- Bifunctional AgOAc/ThioClickFerrophos catalyzed asymmetric 1, 3-dipolar cycloaddition reaction of azomethine ylides to nitroalkenes
- Authors:
- Kimura, Midori
Matsuda, Yukiko
Koizumi, Akihiro
Tokumitsu, Chihiro
Tokoro, Yuichiro
Fukuzawa, Shin-ichi - Abstract:
- Abstract: AgOAc/ThioClickFerrophos (TCF) complex catalyzed the 1, 3-dipolar cycloaddition of azomethine ylides (glycine imino ester) to nitroalkenes. The corresponding endo -cycloadducts (88:12–98:2 endo / exo ) were afforded in good yields with high enantioselectivities, up to 98% ee, without addition of external amine. AgOAc/TCF works as a bifunctional (Lewis acid and base) catalyst. Graphical abstract:
- Is Part Of:
- Tetrahedron. Volume 72:Issue 21(2016)
- Journal:
- Tetrahedron
- Issue:
- Volume 72:Issue 21(2016)
- Issue Display:
- Volume 72, Issue 21 (2016)
- Year:
- 2016
- Volume:
- 72
- Issue:
- 21
- Issue Sort Value:
- 2016-0072-0021-0000
- Page Start:
- 2666
- Page End:
- 2670
- Publication Date:
- 2016-05-26
- Subjects:
- Silver acetate -- P, S-Ligand -- Nitroalkene -- Cycloaddition -- Azomethine ylide
Chemistry, Organic -- Periodicals
547.005 - Journal URLs:
- http://www.elsevier.com/journals ↗
- DOI:
- 10.1016/j.tet.2015.08.002 ↗
- Languages:
- English
- ISSNs:
- 0040-4020
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 8796.850000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 1445.xml