A trigonal prismatic Cu6-pyrazolato complex containing a μ6-F ligand. Issue 47 (13th November 2015)

• Record Type: Journal Article
• Authors: Mathivathanan, Logesh; Al-Ameed, Karrar; Lazarou, Katerina; Trávníček, Zdeněk; Sanakis, Yiannis; Herchel, Radovan; McGrady, John E.; Raptis, Raphael G.
• Is Part Of: Dalton transactions. Volume 44:Issue 47(2015)
• Page Start: 20685
• Page End: 20691
• Publication Date: 2015-11-13
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c5dt03892h
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : The encapsulation of a fluoride ion in a trigonal prismatic CuII6-pyrazolato cage results in a small expansion of the Cu6 -host. Abstract : The encapsulation of a fluoride ion in a trigonal prismatic CuII6-pyrazolato cage results in a small expansion of the Cu6 -host. The structural, electronic and magnetic features of the Cu6 -complex, containing an endohedral fluoride in the rare μ6 -F coordination mode, are compared with those of the parent complex with a vacant Cu6 -cage.