A trigonal prismatic Cu6-pyrazolato complex containing a μ6-F ligand. Issue 47 (13th November 2015) - Mathivathanan, Logesh
Abstract : The encapsulation of a fluoride ion in a trigonal prismatic CuII6-pyrazolato cage results in a small expansion of the Cu6 -host. Abstract : The encapsulation of a fluoride ion in a trigonal prismatic CuII6-pyrazolato cage results in a small expansion of the Cu6 -host. The structural, electronic and magnetic features of the Cu6 -complex, containing an endohedral fluoride in the rare μ6 -F coordination mode, are compared with those of the parent complex with a vacant Cu6 -cage.