Two‐Dimensional Supramolecular Electron Spin Arrays. (22nd January 2013)

• Record Type: Journal Article
• Authors: Wäckerlin, Christian; Nowakowski, Jan; Liu, Shi‐Xia; Jaggi, Michael; Siewert, Dorota; Girovsky, Jan; Shchyrba, Aneliia; Hählen, Tatjana; Kleibert, Armin; Oppeneer, Peter M.; Nolting, Frithjof; Decurtins, Silvio; Jung, Thomas A.; Ballav, Nirmalya
• Is Part Of: Advanced materials. Volume 25:Number 17(2013)
• Page Start: 2404
• Page End: 2408
• Publication Date: 2013-01-22
• Subjects: Materials -- Periodicals; Chemical vapor deposition -- Periodicals; 620.11
• DOI: 10.1002/adma.201204274
• Languages: English
• ISSNs: 0935-9648

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>A bottom‐up approach</bold> is introduced to fabricate two‐dimensional self‐assembled layers of molecular spin‐systems containing Mn and Fe ions arranged in a chessboard lattice. We demonstrate that the Mn and Fe spin states can be reversibly operated by their selective response to coordination/decoordination of volatile ligands like ammonia (NH₃). <boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg1zskdzwq" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>