Hetero‐Epitaxial Approach by Using Labile Coordination Sites to Prepare Catenated Metal–Organic Frameworks with High Surface Areas. Issue 13 (24th February 2014)

• Record Type: Journal Article
• Authors: Zhu, Nianyong; Lennox, Matthew J.; Tobin, Gerard; Goodman, Lisa; Düren, Tina; Schmitt, Wolfgang
• Is Part Of: Chemistry. Volume 20:Issue 13(2014)
• Page Start: 3595
• Page End: 3599
• Publication Date: 2014-02-24
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.201304856
• Languages: English
• ISSNs: 0947-6539

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>A solid‐state approach that takes advantage of the ordered 3D arrangement of active secondary building units allows the preparation of new interlocked MOFs that grow hetero‐epitaxially on the crystal faces of a precursor phase that acts as a "topological blueprint". The synthetic strategy is exemplified by using rigid acetylene‐based ligands to produce highly augmented Cu^II acetate‐based MOFs.</p> </abstract>