Hetero‐Epitaxial Approach by Using Labile Coordination Sites to Prepare Catenated Metal–Organic Frameworks with High Surface Areas. Issue 13 (24th February 2014) - Zhu, Nianyong
Abstract A solid‐state approach that takes advantage of the ordered 3D arrangement of active secondary building units allows the preparation of new interlocked MOFs that grow hetero‐epitaxially on the crystal faces of a precursor phase that acts as a "topological blueprint". The synthetic strategy is exemplified by using rigid acetylene‐based ligands to produce highly augmented CuII acetate‐based MOFs.