Post-synthetic linker installation: an unprecedented strategy to enhance iodine adsorption in metal–organic frameworks. Issue 33 (4th April 2023)

• Record Type: Journal Article
• Authors: Li, Zi-Jian; Ju, Yu; Qiu, Jie; Zhang, Zhi-Hui; Zhang, Linjuan; He, Ming-Yang; Wang, Jian-Qiang; Lin, Jian
• Is Part Of: Chemical communications. Volume 59:Issue 33(2023)
• Page Start: 4958
• Page End: 4961
• Publication Date: 2023-04-04
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/d3cc00278k
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : An unprecedented strategy to enhance iodine adsorption has been developed by post-synthetically installing electron-rich ligands into metal–organic frameworks. Abstract : Post-synthetic linker installation in a single-crystal-to-single-crystal manner was crystallographically demonstrated in thorium-based metal–organic frameworks (Th-MOFs), not only leading to the discovery of an extremely rare framework de-interpenetration, but also representing an unprecedented strategy for boosting iodine adsorption capacity.