Characterization and isolation of an 18-crown-6 complex of potassium hydroxide prepared by milling: application to mechanochemical organic synthesis. (7th March 2023)
- Record Type:
- Journal Article
- Title:
- Characterization and isolation of an 18-crown-6 complex of potassium hydroxide prepared by milling: application to mechanochemical organic synthesis. (7th March 2023)
- Main Title:
- Characterization and isolation of an 18-crown-6 complex of potassium hydroxide prepared by milling: application to mechanochemical organic synthesis
- Authors:
- Vugrin, Leonarda
Halasz, Ivan
Geneste, Hervé - Abstract:
- Abstract : Solid-state supramolecular complexation of potassium cations enables the reactivity of KOH in mechanochemical organic reactions. Abstract : The enhanced mechanochemical reactivity of potassium hydroxide (KOH) in the presence of 18-crown-6 ether is supported by potassium complexation under milling and has been demonstrated in the Henry reaction and SN Ar hydroxylation: in both cases, the desired product is formed within 10 minutes, but requires the presence of the crown ether.
- Is Part Of:
- New journal of chemistry. Volume 47:Number 16(2023)
- Journal:
- New journal of chemistry
- Issue:
- Volume 47:Number 16(2023)
- Issue Display:
- Volume 47, Issue 16 (2023)
- Year:
- 2023
- Volume:
- 47
- Issue:
- 16
- Issue Sort Value:
- 2023-0047-0016-0000
- Page Start:
- 7466
- Page End:
- 7469
- Publication Date:
- 2023-03-07
- Subjects:
- Chemistry -- Periodicals
Chimie -- Périodiques
540 - Journal URLs:
- http://www.rsc.org/ ↗
http://www.rsc.org/is/journals/current/newjchem/njc.htm ↗ - DOI:
- 10.1039/d3nj00364g ↗
- Languages:
- English
- ISSNs:
- 1144-0546
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 6084.319900
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 27069.xml