Low cost and highly dispersed Ce/Na-ZSM-5 catalysts close to atomic dispersion for enhancing formaldehyde oxidation. Issue 17 (17th April 2023)

• Record Type: Journal Article
• Authors: Xu, Zhihao; Ye, Kai-Hang; Zheng, Yuying; Liang, Zhiting; Tang, Tongxin; Zhang, Ying; He, Xiaohui; Ji, Hongbing
• Is Part Of: Dalton transactions. Volume 52:Issue 17(2023)
• Page Start: 5427
• Page End: 5432
• Publication Date: 2023-04-17
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/d3dt00403a
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : Formaldehyde oxidation at room temperature with low-cost catalysts is one of the main development directions of environmental governance. Abstract : Formaldehyde oxidation at room temperature with low-cost catalysts is one of the main development directions of environmental governance. Herein, we developed a low-cost and superior performance highly dispersed Ce on Na-ZSM-5 (Ce/Na-ZSM-5) catalyst, which is close to atomic dispersion for indoor formaldehyde (HCHO) oxidation at low temperature. The highly dispersed catalyst that was similar to atomic dispersion was characterized by EXAFS and AC HAADF-STEM. The optimal Ce/Na-ZSM-5 displays high HCHO removal performance (95%, at room temperature), as well as 100 h stable testing (∼90% HCHO removal). In addition, a reasonable reaction mechanism of the HCHO catalytic oxidation is proposed based on the in situ DRIFT spectra and DFT calculation. This work provides a new way to design an efficient catalyst for the complete oxidation of formaldehyde.