Nitrogen-doped carbon decorated 3D NiCoSe2 micro-flowers as high-performance anode materials for lithium-ion batteries. Issue 16 (11th April 2023)

• Record Type: Journal Article
• Authors: Xu, Jing; Xie, Lingling; Niu, Yu; Chen, Honghua; Zhang, Yuhan; Jiang, Yubin; Han, Qing; Qiu, Xuejing; Miao, Yongxia; Zhu, Limin; Cao, Xiaoyu
• Is Part Of: Physical chemistry chemical physics. Volume 25:Issue 16(2023)
• Page Start: 11530
• Page End: 11544
• Publication Date: 2023-04-11
• Subjects: Chemistry, Physical and theoretical -- Periodicals; 541.3
• DOI: 10.1039/d3cp00228d
• Languages: English
• ISSNs: 1463-9076

Abstract

Abstract : 3D NiCoSe2 /NC micro flowers were studied as high-performance anode materials for lithium-ion batteries. CoNiSe2 /NC not only have the high conductivity of nickel and cobalt, but also inherit the relatively stable skeleton structure of MOFs. Abstract : Compared with monometallic selenides, bimetallic selenides have better synergistic effects and more abundant active sites for electrochemical reactions. As an important member of the transition metal oxide family, NiCoSe2 has been widely used in energy storage devices and has shown excellent electrochemical performance. So in this paper, nitrogen-doped carbon decorated NiCoSe2 composites (NiCoSe2 /NC-700, NiCoSe2 /NC-800, and NiCoSe2 /NC-900) with a microflower structure were synthesized by calcining nickel–cobalt bimetallic organic skeleton materials at different temperatures, and were used as anode materials for rechargeable lithium-ion batteries. Because the MOF precursor has many advantages such as structural controllability, and a bimetal synergistic effect, the test results showed that the prepared NiCoSe2 /NC composites have a special morphology, outstanding electrical conductivity, excellent lithium storage performance and electrochemical cycling performance in the process of being used as anode materials for lithium-ion batteries. The NiCoSe2 /NC-800 materials displayed a high initial capacity (2099.8/1084.3 mA h g −1 ), and still maintained a high capacity (1041.2/989.9 mA h g −1 ) after 100 cycles at a current density of 0.1 A g −1 and in the voltage range of 0.01–3.0 V. In addition, at high current densities of 0.5 A g −1 and 1.0 A g −1, the increased capacity of NiCoSe2 /NC composites may be due to the activation of electrodes and the pseudocapacitance during cycling. Through ex situ XRD experiments, the lithium storage mechanism of the NiCoSe2 /NC-800 electrode material during cycling was further studied, and NiCoSe2 /NC-800 was continuously converted into Ni, Co, and Li2 Se during cycling.