Blue emitters with various electron-donors attached to the 9-phenyl-9-phosphafluorene oxide (PhFIOP) moiety and their thermally activated delayed fluorescence (TADF) behavior. (15th March 2023)

• Record Type: Journal Article
• Authors: Chen, Xi; Liu, Siqi; Sun, Yuling; Zhong, Daokun; Feng, Zhao; Yang, Xiaolong; Su, Bochao; Sun, Yuanhui; Zhou, Guijiang; Jiao, Bo; Wu, Zhaoxin
• Is Part Of: Materials chemistry frontiers. Volume 7:Number 9(2023)
• Page Start: 1841
• Page End: 1854
• Publication Date: 2023-03-15
• Subjects: Materials science -- Periodicals; Chemistry -- Periodicals; 540
• DOI: 10.1039/d2qm01339h
• Languages: English
• ISSNs: 2052-1529

Abstract

Abstract : Blue emitters with various electron-donors attached to the 9-phenyl-9-phosphafluorene oxide (PhFIOP) moiety and their thermally activated delayed fluorescence (TADF) behavior. Abstract : A series of luminescent molecules have been developed through attaching various electron-donors to the 4- and/or 6-positions of the 9-phenyl-9-phosphafluorene oxide (PhFIOP) moiety. Furthermore, their photophysical, thermal, electrochemical and electroluminescent properties have been characterized in detail. Critically, it has been found that introducing two electron-donors to the 4- and 6-positions of the PhFIOP moiety can furnish a smaller singlet–triplet energy gap (Δ E ST ) than the analogues with a single electron-donor at the 4-position of the PhFIOP moiety. Hence, PhFIOP-based emitters with two phenoxazine and two acridine moieties as electron-donors can show thermally activated delayed fluorescence (TADF) behavior with a high reverse inter-system crossing constant ( k RISC ) in the order of 10 6 s −1 . In contrast, TADF features cannot be observed in PhFIOP-based emitters with only one electron-donor. In addition, these luminescent molecules can also exhibit high photoluminescence quantum yields (PLQYs) ranging from 70% to 90% in doped films, which results in excellent electroluminescence (EL) performance. To validate this idea, monochromatic OLED devices have been fabricated and the results show a maximum current efficiency ( η L ) of 55.6 cd A −1, a power efficiency ( η P ) of 49.2 lm W −1, and an external quantum efficiency ( η ext ) of 27.3%. Moreover, blue EL emission has also been achieved with CIE (0.17, 0.14) as well as high EL efficiencies of 18.7 cd A −1, 15.6 lm W −1, and 21.9%, respectively. Thus, these PhFIOP-based emitters will enrich the structural diversity of APO-type TADF molecules with high EL efficiency.