Global reanalysis products cannot reproduce seasonal and diurnal cycles of tropospheric ozone in the Congo Basin. (1st July 2023)

• Record Type: Journal Article
• Authors: Vieira, Inês; Verbeeck, Hans; Meunier, Félicien; Peaucelle, Marc; Sibret, Thomas; Lefevre, Lodewijk; Cheesman, Alexander W.; Brown, Flossie; Sitch, Stephen; Mbifo, José; Boeckx, Pascal; Bauters, Marijn
• Is Part Of: Atmospheric environment. Volume 304(2023)
• Publication Date: 2023-07-01
• Subjects: Tropospheric ozone -- O3 -- Reanalysis -- In situ observations -- Congo Basin; Air -- Pollution -- Periodicals; Air -- Pollution -- Meteorological aspects -- Periodicals; 551.51
• DOI: 10.1016/j.atmosenv.2023.119773
• Languages: English
• ISSNs: 1352-2310

Abstract

Abstract: Tropospheric ozone (O3 ) is a secondary pollutant and a greenhouse gas with a positive radiative forcing. Many studies have documented its negative impacts on plant growth and human health. Historically, studies have focused on determining levels of exposure in mid- and high-latitude regions. In the tropics, high O3 concentrations are expected due to large concurrent and future precursor emissions. In Africa, seasonal biomass burning (from both natural and anthropogenic fires) during the dry season plays a crucial role in O3 precursor production. However, O3 observational studies in tropical Africa are currently missing. To fill this major knowledge gap, we established in November 2019 a continuous monitoring of near-surface O3 in the Congo Basin at the Yangambi research centre in the Democratic Republic of the Congo. Using this unique dataset in the heart of the second-largest tropical forest in the world, we assessed the ability of current remote sensing products to capture the magnitude and temporal dynamics of in situ tropospheric O3 concentrations, especially O3 concentration variation between dry and wet seasons until March of 2022. We compared near-surface atmospheric O3 measurements collected in Yangambi and four different reanalysis products: European Centre for Medium-Range Weather Forecasts Reanalysis (ECMWF) v5 (ERA5), Copernicus Atmospheric Monitoring Service reanalysis (CAMSRA), Modern-Era Retrospective Analysis for Research and Applications version 2 (MERRA-2) and Japanese Reanalysis (JRA-55). The results show that reanalysis products overestimated the magnitude of near-surface O3 across the region with a mean bias of 27.3 ppbv, 19.9 ppbv, 10.8 ppbv and 1.0 ppbv for ERA5, CAMSRA, MERRA-2 and JRA-55, respectively. ERA5 and CAMSRA reanalysis were the only products able to capture, to some extent, the observed annual variation, showing higher O3 concentrations during dry season months, despite the inability to reproduce the daily cycle of near-surface O3 . Highlights: The first-ever dataset of near-surface ozone was collected in the core of the African tropical forests. It fills a critical gap in a relevant area as ozone has been thought to reach large concentrations in central Africa. Access the ability of state-of-the-art reanalysis products to capture the magnitude and temporal dynamics of in situ O3. The reanalysis products fail to reproduce the seasonality and the daily cycles of tropospheric ozone.