Processing‐structure–property relationships in the fabrication of extrusion electroactive poly(vinylidenefluoride) filaments. Issue 21 (25th March 2023)

• Record Type: Journal Article
• Authors: Saleh, Aya A.; Melenka, Garrett W.; Leung, Siu Ning
• Is Part Of: Journal of applied polymer science. Volume 140:Issue 21(2023)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2023-03-25
• Subjects: electroactive PVDF -- electromechanical energy harvesting -- extrusion -- microcompounder; Polymers -- Periodicals; Polymerization -- Periodicals; 668.9
• DOI: 10.1002/app.53885
• Languages: English
• ISSNs: 0021-8995

Abstract

Abstract: Poly(vinylidenefluoride) with enhanced electroactive properties is of great interest in energy harvesting and sensing applications. This study aims to elucidate the effects of processing parameters in extrusion, using a desktop extruder or a microcompounder, on the polymorphism of the fabricated poly(vinylidenefluoride) filaments. All samples were characterized by differential scanning calorimetry, Fourier‐transform infrared spectroscopy, and electromechanical testing. Statistical analyses were conducted to correlate the processing parameters with the poly(vinylidenefluoride) filaments' crystal structures. Experimental results revealed that the optimal extrusion temperature at 220°C and stretching ratio of 4.5 to 6.5 would yield poly(vinylidenefluoride) filaments with a degree of crystallinity of up to 58% of which 80% is β‐phase crystals. The finding of this manuscript has the potential to promote the use of poly(vinylidenefluoride) filaments in the fused filament fabrication. Abstract : An illustration of the PVDF process‐structure‐property relationship.