Copper‐Catalyzed 1, 4‐Addition of a Silicon Nucleophile to Azadienes. Issue 16 (30th March 2023)

• Record Type: Journal Article
• Authors: Chu, Wen‐Dao; Wang, Chun‐Mei; Zhan, Jie; Zeng, Ya‐Li; Liu, Yong; Chen, Bo; Zhang, Kaiming; He, Cheng‐Yu; Liu, Quan‐Zhong
• Is Part Of: European journal of organic chemistry. Volume 26:Issue 16(2023)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2023-03-30
• Subjects: 1, 4-addition -- azadienes -- benz-ofuran -- copper-catalyzed -- PhMe2SiBpin; Chemistry, Organic -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Bioorganic chemistry -- Periodicals; Chemistry, Physical organic -- Periodicals; 547
• DOI: 10.1002/ejoc.202300210
• Languages: English
• ISSNs: 1434-193X

Abstract

Abstract: Copper‐catalyzed 1, 4‐addition of a silicon nucleophile to azadienes is reported. This method facilely provided a wide variety of dibenzylic silane derivatives in good to excellent yields. The important practical features are the use of a cheap catalytic system, mild reaction conditions, and broad substrate scope. Abstract : Here developed a copper‐catalyzed 1, 4‐addition of a silicon nucleophile to azadienes This method facilely provided a wide variety of dibenzylic silane derivatives in good to excellent yields.