Aiming for dynamic behaviours of molecular metal chains. Issue 5 (1st December 2022)

• Record Type: Journal Article
• Authors: Tanase, Tomoaki; Nakamae, Kanako; Ura, Yasuyuki; Nakajima, Takayuki
• Is Part Of: Dalton transactions. Volume 52:Issue 5(2023)
• Page Start: 1147
• Page End: 1158
• Publication Date: 2022-12-01
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/d2dt03442e
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : This paper focuses on dynamic behaviors of the Pd chains supported by linear tetraphosphines, and current development on fine-tuning of metal chains by introducing heterometal atoms, which are considered promising dynamic components. Abstract : The dynamical functions of molecular metal chains, that could be derived from unique physical and chemical properties coupled with self-assembly of metal chain components, have largely been unexplored, and this review paper focuses on the dynamic behaviours of Pd chains supported by linear tetraphosphines, meso - and rac -Ph2 PCH2 P(Ph)CH2 P(Ph)CH2 PPh2 recently reported, and the current development on fine-tuning of metal chains by introducing heterometal atoms, i.e. heterometallic molecular metal chains, that are considered as promising dynamical components in the next generation.