Immiscible PHB/PBS and PHB/PBSA blends: morphology, phase composition and modelling of elastic modulus. Issue 1 (21st August 2021)

• Record Type: Journal Article
• Authors: Righetti, Maria Cristina; Cinelli, Patrizia; Aliotta, Laura; Bianchi, Elisa; Tricoli, Fabio; Seggiani, Maurizia; Lazzeri, Andrea
• Is Part Of: Polymer international. Volume 71:Issue 1(2022)
• Page Start: 47
• Page End: 56
• Publication Date: 2021-08-21
• Subjects: immiscible blends -- crystallization -- co‐continuous morphology -- physical adhesion -- elastic modulus; Plastics -- Periodicals; Polymers -- Periodicals; Polymerization -- Periodicals; 547.7
• DOI: 10.1002/pi.6282
• Languages: English
• ISSNs: 0959-8103

Abstract

Abstract: This paper reports the thermal, morphological and mechanical properties of environmentally friendly poly(3‐hydroxybutyrate) (PHB)/poly(butylene succinate) (PBS) and PHB/poly[(butylene succinate)‐ co ‐(butylene adipate)] (PBSA) blends, prepared by melt mixing. The blends are known to be immiscible, as also confirmed by the thermodynamic analysis here presented. A detailed quantification of the crystalline and amorphous fractions was performed, in order to interpret the mechanical properties of the blends. As expected, the ductility increased with increasing PBS or PBSA amount, but in parallel the decrease in the elastic modulus appeared limited. Surprisingly, the elastic modulus was found properly described by the rule of mixtures in the whole composition range, thus attesting mechanical compatibility between the two blend components. This unusual behavior has been explained as due to co‐continuous morphology, present in a wide composition range, but also at the same time as the result of shrinkage occurring during sequential crystallization of the two components, which can lead to physical adhesion between matrix and dispersed phase. For the first time, the elastic moduli of the crystalline and mobile amorphous fractions of PBS and PBSA and of the mobile amorphous fraction of PHB at ambient temperature have been estimated through a mechanical modelling approach. © 2021 The Authors. Polymer International published by John Wiley & Sons Ltd on behalf of Society of Industrial Chemistry. Abstract : The elastic moduli of (i) the crystalline and mobile amorphous fractions of PBS and PBSA and (ii) the mobile amorphous fraction of PHB have been estimated through a mechanical modelling treatment.