Electrochemical promoted CH bond chlorination of sulfoxonium ylides. (12th January 2023)

• Record Type: Journal Article
• Authors: Zhang, Li-Ming; Fu, Zi-Hao; Yuan, Da-Fu; Guo, Ming-Zhong; Li, Ming; Wen, Li-Rong; Zhang, Lin-Bao
• Is Part Of: Tetrahedron letters. Volume 114(2023)
• Publication Date: 2023-01-12
• Subjects: Electrochemistry -- Sulfoxonium ylides -- Chlorination; Chemistry, Organic -- Periodicals; 547.005
• DOI: 10.1016/j.tetlet.2022.154244
• Languages: English
• ISSNs: 0040-4039

Abstract

Graphical abstract: Abstract: The first electrochemical promoted CH bond chlorination of sulfoxonium ylides was accomplished using magnesium chloride as the chlorine source, as well as a supporting electrolyte. This method does not require transition metal catalysts, external oxidants, and electrolytes, providing a green and mild route for the functionalization of sulfoxonium ylides.