An open-source environmental chamber for materials-stability testing using an optical proxy. (20th February 2023)

• Record Type: Journal Article
• Authors: Keesey, Rodolfo; Tiihonen, Armi; Siemenn, Alexander E.; Colburn, Thomas W.; Sun, Shijing; Putri Hartono, Noor Titan; Serdy, James; Zeile, Margaret; He, Keqing; Gurtner, Cole A.; Flick, Austin C.; Batali, Clio; Encinas, Alex; Naik, Richa R.; Liu, Zhe; Oviedo, Felipe; Peters, I. Marius; Thapa, Janak; Parker Tian, Siyu Isaac; Dauskardt, Reinhold H.; Norquist, Alexander J.; Buonassisi, Tonio
• Is Part Of: Digital discovery. Volume 2:Number 2(2023)
• Page Start: 422
• Page End: 440
• Publication Date: 2023-02-20
• Subjects: Chemistry -- Data processing -- Periodicals; Medical sciences -- Data processing -- Periodicals; Machine learning -- Periodicals; 542.85
• DOI: 10.1039/d2dd00089j
• Languages: English
• ISSNs: 2635-098X

Abstract

Abstract : Designs for an open source environmental chamber for stability testing of metal halide perovskites and other materials using optical degradation fingerprints. The design suite can accommodate bulk samples, thin films or full photovoltaic devices. Abstract : This study is motivated by the desire to produce a low-cost, high-precision, high-throughput environmental chamber to test materials and devices under elevated humidity, temperature, and light. This paper documents the creation of an open-source tool with a bill of materials as low as US$2, 000, and the subsequent evolution of three second-generation tools installed at three different universities spanning thin films, bulk crystals, and thin-film solar-cell devices. We introduce an optical proxy measurement to detect real-time phase changes in materials. We present correlations between this optical proxy and standard X-ray diffraction measurements, describe some edge cases where the proxy measurement fails, and report key learnings from the technology-translation process. By sharing lessons learned, we hope that future open-hardware development and translation efforts can proceed with reduced friction. Throughout the paper, we provide examples of scientific impact, wherein participating laboratories used their environmental chambers to study and improve the stabilities of halide-perovskite materials. All generations of hardware bills of materials, assembly instructions, and operating codes are available in open-source repositories.