Porous zeolitic imidazolate frameworks assembled with highly-flattened tetrahedral copper(ii) centres and 2-nitroimidazolates. Issue 27 (16th March 2023)

• Record Type: Journal Article
• Authors: Jung, Cheolwon; Choi, Sang Beom; Park, Jaewoo; Jung, Minji; Kim, Jonghoon; Oh, Hyunchul; Kim, Jaheon
• Is Part Of: Chemical communications. Volume 59:Issue 27(2023)
• Page Start: 4040
• Page End: 4043
• Publication Date: 2023-03-16
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/d2cc06797h
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : Cu-ZIF-gis has 2.4 Å cylindrical pores that can adsorb H2 gas, and Cu-ZIF-rho has 19.8 Å cages with a BET surface area of 1320 m 2 g −1 . Abstract : Cu(ii )-based zeolitic imidazolates (Cu-ZIFs), Cu-ZIF-gis and -rho, formulated as Cu(nIm)2 (nIm = 2-nitroimidazolate) have highly-flattened tetrahedral coordination geometry. Cu-ZIF-gis has 2.4 Å cylindrical pores that can adsorb H2 gas, and Cu-ZIF-rho has 19.8 Å cages with a BET surface area of 1320 m 2 g −1 .