Applications of analytical electron microscopy to guide the design of boron carbide. Issue 5 (30th July 2021)

• Record Type: Journal Article
• Authors: Marvel, Christopher J.; Yang, Qirong; Walck, Scott D.; Xie, Kelvin Y.; Behler, Kristopher D.; LaSalvia, Jerry C.; Watanabe, Masashi; Haber, Richard A.; Harmer, Martin P.
• Is Part Of: Journal of the American Ceramic Society. Volume 105:Issue 5(2022)
• Page Start: 2990
• Page End: 3007
• Publication Date: 2021-07-30
• Subjects: ζ‐factor microanalysis -- boron carbide -- grain boundaries -- transmission electron microscopy; Ceramics -- Periodicals; 620.1405
• DOI: 10.1111/jace.18039
• Languages: English
• ISSNs: 0002-7820

Abstract

Abstract: Compositional analysis of boron carbide on nanometer length scales to examine or interpret atomic mechanisms, for example, solid‐state amorphization or grain‐boundary segregation, is challenging. This work reviews advancements in high‐resolution microanalysis to characterize multiple generations of boron carbide. First, ζ‐factor microanalysis will be introduced as a powerful (scanning) transmission electron microscopy ((S)TEM) analytical framework to accurately characterize boron carbide. Three case studies involving the application of ζ‐factor microanalysis will then be presented: (1) accurate stoichiometry determination of B‐doped boron carbide using ζ‐factor microanalysis and electron energy loss spectroscopy, (2) normalized quantification of silicon grain‐boundary segregation in Si‐doped boron carbide, and (3) calibration of a scanning electron microscope X‐ray energy‐dispersive spectroscopy (XEDS) system to measure compositional homogeneity differences of B/Si‐doped arc‐melted boron carbides in the as‐melted and annealed conditions. Overall, the improvement and application of advanced analytical tools have helped better understand processing–microstructure–property relationships and successfully manufacture high‐performance ceramics.