A novel method to remove nitrogen from sewage sludge during hydrothermal carbonization via inhibiting Maillard reaction. Issue 2 (April 2023)

• Record Type: Journal Article
• Authors: Xu, Zhixiang; Tan, Yi; Ma, Xueqin; Wu, Shiyong; Zhang, Bo; Luque, Rafael
• Is Part Of: Journal of environmental chemical engineering. Volume 11:Issue 2(2023)
• Publication Date: 2023-04
• Subjects: Sewage sludge -- Deep eutectic solvents -- Hydrothermal carbonization -- Nitrogen removal; Chemical engineering -- Environmental aspects -- Periodicals; Environmental engineering -- Periodicals; Chemical engineering -- Environmental aspects; Environmental engineering; Periodicals; 660.0286
• DOI: 10.1016/j.jece.2023.109342
• Languages: English
• ISSNs: 2213-2929

Abstract

Abstract: In order to prepare low nitrogen content hydrochar, deep eutectic solvents (DES) have been utilized as a green solvent to remove nitrogen from sewage sludge (SS) during the hydrothermal carbonization (HTC) processing. Compared to without DES, the maximum removal efficiency of nitrogen in hydrochar can increase as high as 69.49% at 210 o C when choline chloride and oxalic acid are employed as DES. Results demonstrate that different DES systems possess different capability to remove nitrogen, and DES offers the advantages to degrade floc structure of SS, thus inhibiting Maillard reaction during the HTC. It is revealed that organic matter releasing from floc structure within SS, low polysaccharide content, as well as fast caramelization under basic condition are vital factors to retard Maillard reaction to obtain low nitrogen content hydrochar from SS. In addition, the possible removal pathways are also analyzed and proposed in this investigation. Graphical Abstract: ga1 Highlights: DES could dissolve proteins during the HTC of SS. Disruption of floc structure of SS was key to inhibit Maillard reaction. DES(CO) has a stronger capability than DES(CU) to disrup the floc structure of SS. DES(CO) promoted hydrolysis of organic matter and increased carbonization degree of biochar.