An ultra-strong and ductile crystalline-amorphous nanostructured surface layer on TiZrHfTaNb0.2 high-entropy alloy by laser surface processing. (March 2023)

• Record Type: Journal Article
• Authors: Luo, Jiasi; Sun, Wanting; Liang, Dingshan; Yang, Wenqing; Chan, K.C.; Ren, Fuzeng; Yang, Xu-Sheng
• Is Part Of: Materials & design. Volume 227(2023)
• Publication Date: 2023-03
• Subjects: Laser surface remelting -- High-entropy alloy -- Hetero-nanostructure -- Crystalline-amorphous nanostructure -- Micro-pillar compression tests; Materials -- Periodicals; Engineering design -- Periodicals; Matériaux -- Périodiques; Conception technique -- Périodiques; Electronic journals; 620.11
• DOI: 10.1016/j.matdes.2023.111710
• Languages: English
• ISSNs: 0264-1275

Abstract

Graphical abstract: Highlights: A crystalline-amorphous nanostructured top surface layer is developed on a high-entropy alloy by laser surface processing. The phase decomposition-mediated mechanisms forming the crystalline-amorphous nanostructured surface layer are uncovered. Localized micro-pillar compression tests on surface layer shows an ultrahigh yield strength and a good compression strain . The co-deformation cooperative actions include dislocation activities in nanograins but crystallization in amorphous GBs. The co-deformation cooperative effects subsequently lead to the grain coarsening via GB-mediated plasticity. Abstract: Heterogeneous crystalline-amorphous nanostructures have been documented to show superior strength-ductility synergy via the co-deformation cooperative effects of nanograins and amorphous grain boundaries. In this work, a facile laser surface remelting technique with rapid cooling rate was successfully developed to fabricate a ∼ 100 μm-thick gradient nanostructured layer accompanied by phase decomposition on a TiZrHfTaNb0.2 high-entropy alloy, where a ∼ 5 μm-thick crystalline-amorphous nanostructured top surface layer with an average grain size of ∼ 7 nm was obtained. Such crystalline-amorphous nanostructured layer shows an ultrahigh yield strength of ∼ 6.0 GPa and a compression strain of ∼ 25 % during the localized micro-pillar compression tests. The atomic observations reveal that co-deformation cooperative mechanisms include the well-retained dislocation activities in nanograins but crystallization in amorphous grain boundaries, which subsequently lead to the grain coarsening via grain boundary-mediated plasticity. This study sheds light on the development of high-performance high-entropy alloys with novel crystalline-amorphous nanostructures and provides significant insight into their plastic deformation mechanisms.