A comprehensive cognition for the capacity fading mechanism of FeS2 in argyrodite‐based all‐solid‐state lithium battery. Issue 4 (9th February 2023)

• Record Type: Journal Article
• Authors: Wu, Zhan; Zhang, Wenkui; Xia, Yang; Huang, Hui; Gan, Yongping; He, Xinping; Xia, Xinhui; Zhang, Jun
• Is Part Of: EcoMat. Volume 5:Issue 4(2023)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2023-02-09
• Subjects: all‐solid‐state lithium battery -- capacity fading mechanism -- conversion cathode -- electrochemical reaction pathway -- FeS2; Materials -- Environmental aspects -- Periodicals; Clean energy -- Periodicals; 621.042
• DOI: 10.1002/eom2.12327
• Languages: English
• ISSNs: 2567-3173

Abstract

Abstract: Sulfide solid state electrolyte (SSE) possesses high ionic conductivity and great processability but suffers from narrow electrochemical window. Conversion sulfide cathode FeS2 has higher specific capacity and moderate redox potential, making it appropriate toward sulfide SSE. However, the complex reaction pathway and capacity fading mechanism in FeS2 are rarely studied, especially in all‐solid‐state lithium battery (ASSLB). Herein, argyrodite sulfide SSE is paired with FeS2 to investigate the electrochemical reaction pathways and the capacity fade mechanism. Instead of single conversion reaction, an anionic redox driven reaction of FeS2 is revealed. The oxidization of Li2 S vanishes and large quantity of inactive Li2 S accumulates to cause the interfacial deterioration, along with the stress concentration during cycling, which leads to the rapid capacity fade of FeS2 . Finally, a simple strategy of slurry‐coated composite electrode with highly conductive network is proposed to direct the uniform deposition of Li2 S and alleviate the stress concentration. Abstract : Electrochemical reaction pathway and capacity fading mechanism of FeS2 in sulfide‐based ASSLB.