Perovskite CsPbBr3 Single‐Crystal Detector Operating at 1010 Photons s−1 mm−2 for Ultra‐High Flux X‐ray Detection. Issue 7 (29th January 2023)

• Record Type: Journal Article
• Authors: Pan, Lei; Pandey, Indra Raj; Miceli, Antonino; Klepov, Vladislav V.; Chung, Duck Young; Kanatzidis, Mercouri G.
• Is Part Of: Advanced optical materials. Volume 11:Issue 7(2023)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2023-01-29
• Subjects: perovskite CsPbBr 3 -- polarization -- synchrotron X‐ray -- X‐ray detector; Optical materials -- Periodicals; Photonics -- Periodicals; 620.11295
• DOI: 10.1002/adom.202202946
• Languages: English
• ISSNs: 2195-1071

Abstract

Abstract: Semiconductors for detecting hard radiation are confronted with considerable problems when operating at high photon fluxes. A perovskite CsPbBr3 single‐crystal detector capable of operating at X‐ray fluxes of up to 10 10 photons s −1 mm −2 with beam area ≤ 0.25 mm 2 at 58.61 keV for current‐mode X‐ray detection is reported. The spectrometer‐grade melt‐grown CsPbBr3 detectors show a gamma‐ray energy resolution of ~7.5% at 122 keV for 57 Co and dark current as low as 4.3 nA (0.5 nA mm −2 ) at a reverse bias voltage of 200 V (118 V mm −1 ). The detector is tested at X‐ray energies of 8.2, 10, and 58.61 keV at a synchrotron light source under a reverse bias voltage of up to 1000 V (588 V mm −1 ). Under a sufficiently high bias voltage and within several hundreds of seconds X‐ray exposure, good photocurrent linearity (goodness of fit R 2 > 0.99) and reproducibility are obtained up to a flux of ≈10 10 photons s −1 mm −2 at beam area 0.25 mm 2 with Lower Limit of Detection of ≈10 5 photons s −1 mm −2 and Charge Collection Efficiency of ≈100% for 58.61 keV X‐rays. Accordingly, wide application of CsPbBr3 detectors in high‐flux X‐ray detection is anticipated. Abstract : The ability of the perovskite CsPbBr3 single crystal detector for ultra‐high flux X‐ray detection is demonstrated. The CsPbBr3 detector can be operated up to X‐ray flux of ≈10 10 photons s −1 mm −2 at X‐ray energy 58.6 keV with good photocurrent linearity (goodness of fit R 2 > 0.99) and reproducibility in several hundreds of seconds.