Experimental and mechanism investigation on flowability and wax deposition of waxy crude oil with dissolved CH4 by pressurized laboratory apparatus. (1st July 2023)

• Record Type: Journal Article
• Authors: Zhu, Haoran; Lei, Yun; Li, Chuanxian; Yao, Bo; Yang, Fei; Li, Shuangshuang; Peng, Haoping; Yu, Pengfei
• Is Part Of: Fuel. Volume 343(2023)
• Publication Date: 2023-07-01
• Subjects: Flowability -- Wax deposition -- Pressure -- Mechanism -- Laboratory apparatus; Fuel -- Periodicals; Coal -- Periodicals; Coal; Fuel; Periodicals; 662.6
• DOI: 10.1016/j.fuel.2023.127907
• Languages: English
• ISSNs: 0016-2361

Abstract

Graphical abstract: Highlights: Develop a series of pressurized laboratory apparatus for dissolved gas crude oil. CH4 can reduce wax deposition rate, but raise WAT and wax content of wax deposit. Raising dissolved CH4 pressure reduces deposit mass but raises mass of diffused wax. Molecular diffusion, dynamic gelation and stripping effect are dominant mechanisms. Abstract: In offshore oilfields, crude oils often contain dissolved gas, and are unavoidably transported under pressure. However, the flowability and wax deposition of crude oils with dissolved gas are rarely investigated. In this paper, Methane (CH4 ) was used as a similar substitute for the dissolved gas in crude oils, and a series of pressurized laboratory apparatuses were developed to study the influencing mechanism of dissolved CH4 on the flowability and wax deposition of Changqing waxy crude oil. It was found that with the increase of the dissolved CH4 pressure, the crude oil flowability was improved, and the wax deposition rate was inhibited. However, the wax appearance temperature (WAT), the average wax content of wax deposits, and the mass of wax diffused into wax deposits all increased accordingly. This was mainly attributed to the influence of dissolved CH4, which can effectively increase the intermolecular distance between wax molecules, decrease the intermolecular forces, and weaken the strength of wax crystals to overlap each other. The improvement of rheological properties, on the one hand, promotes the diffusion of wax molecules, which leads to the increase in the mass of wax diffused into wax deposits; on the other hand, it increases the wax content required for the formation of wax deposits according to the dynamic gelation mechanism, thus resulting in the decrease of wax deposition rate. Also, the wax stripping effect during the deposition and depressurization processes cannot be ignored. The research results have guiding significance for the optimal design of the gathering and transportation pipeline network and the calculation of wax deposition.