Aggregation-induced circularly polarized phosphorescence of Pt(ii) complexes with an axially chiral BINOL ligand. Issue 27 (14th March 2023)

• Record Type: Journal Article
• Authors: Tauchi, Daiki; Koida, Taiki; Nojima, Yuki; Hasegawa, Masahi; Mazaki, Yasuhiro; Inagaki, Akiko; Sugiura, Ken-ichi; Nagaya, Yuki; Tsubaki, Kazunori; Shiga, Takuya; Nagata, Yuuya; Nishikawa, Hiroyuki
• Is Part Of: Chemical communications. Volume 59:Issue 27(2023)
• Page Start: 4004
• Page End: 4007
• Publication Date: 2023-03-14
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/d2cc06198h
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : A pair of chiral Pt(ii ) complexes exhibiting aggregation-induced phosphorescence and circularly polarized luminescence have been synthesized and characterized. Abstract : A pair of chiral Pt(ii ) complexes coordinated by simple BINOL and bipyridine ligands displaying aggregation-induced phosphorescence and circularly polarized luminescence were characterized by X-ray crystallography and absorption and emission spectroscopies. The emission of the powder sample was reddish whereas the thin film dispersed in PMMA ( f Pf = 1 wt%) exhibited a white emission.