The controllable synthesis of urchin-shaped hierarchical superstructure MOFs with high catalytic activity and stability. Issue 70 (10th August 2021)

• Record Type: Journal Article
• Authors: Wang, Zhanke; Ge, Lei; Zhang, Guangxu; Chen, Yao; Gao, Rongrong; Wang, Hao; Zhu, Zhonghua
• Is Part Of: Chemical communications. Volume 57:Issue 70(2021)
• Page Start: 8758
• Page End: 8761
• Publication Date: 2021-08-10
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/d1cc03547a
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : The sizes of rod-shaped bulk MOFs could be decreased to the nanoscale via using metal oxides as precursors, and then the as-obtained nanosized MOFs could be self-assembled to form urchin-shaped superstructure MOFs via changing the dosage of ligands. Abstract : A novel dissolution–crystallization-attachment strategy was developed to synthesize urchin-shaped superstructure metal–organic frameworks (MOFs) with self-assembled one-dimensional nanorods. The superstructure MOFs not only inherited the high activity of nanosized MOFs but also displayed the high stability of microsized MOFs.