Understanding water slippage through carbon nanotubes. Issue 27 (30th June 2021)

• Record Type: Journal Article
• Authors: Ma, Cong; Chen, Yun; Sun, Guo En; Li, Quan Ming; Gao, Wang; Jiang, Qing
• Is Part Of: Physical chemistry chemical physics. Volume 23:Issue 27(2021)
• Page Start: 14737
• Page End: 14745
• Publication Date: 2021-06-30
• Subjects: Chemistry, Physical and theoretical -- Periodicals; 541.3
• DOI: 10.1039/d1cp01148k
• Languages: English
• ISSNs: 1463-9076

Abstract

Abstract : The predominant role of hydrogen bonds in the continuum–subcontinuum transition for water slippage in carbon nanotubes. Abstract : It is a formidable challenge to understand water slippage through carbon nanotubes (CNTs), despite its great significance in fundamental research and technology. Herein, we propose an effective scheme to describe water slippage properties by extending two friction models – the phononic friction model and Einstein's diffusion model, both relying on the potential corrugation of water slippage. Our scheme effectively captures the tube-size effect on the viscosity and slippage of water molecules through CNTs. It also identifies the experimentally reported size-dependent transition from continuum to sub-continuum flow and further reveals that this transition is likely to be determined by the hydrogen bond instead of the structural transition or entropic change. Besides, the size-dependence of slip lengths is found to be controllable by temperature. Our methods are thus expected to be a useful basis for further studies on substance transport under confinement.