Pyrolysis and gasification at water resource recovery facilities: Status of the industry. (17th March 2022) - Winchell, Lloyd J.
Abstract: Wastewater treatment generates solids requiring subsequent processing. Costs and contaminant concerns (e.g., per‐ and polyfluoroalkyl substances [PFAS]) are challenging widely used landfilling and land application practices. These circumstances are partly driving the re‐emergence of pyrolysis and gasification technologies along with beneficial reuse prospects of the char solid residual. Previously, technologies experienced operational challenges leading to revised configurations, such as directly coupling a thermal oxidizer to the reactor to destroy tar forming compounds. This paper provides an overview of pyrolysis and gasification technologies, characteristics of the char product, air emission considerations, and potential fate of PFAS and other pollutants through the systems. Results from a survey of viable suppliers illustrate differences in commercially available options. Additional research is required to validate performance over the long‐term operation and confirm contaminant fate, which will help determine whether resurging interest in pyrolysis and gasification warrants widespread adoption. Practitioner Points: Pyrolysis and gasification systems are re‐emerging in the wastewater industry. Direct coupling of thermal oxidizers and other modifications offered by contemporary systems aim to overcome past failures. Process conditions when coupled with a thermal oxidizer will likely destroy most organic contaminants, including PFAS, but requires additional research. Three full‐scale facilities recently operated, several in construction or design that will provide operating experience for widespread technology adoption consideration. Abstract : Pyrolysis and gasification systems in wastewater treatment applications are garnering renewed interest. Rising costs for solid residual handling, emerging contaminants, and beneficial reuse of residuals provided technology suppliers incentive to overcome historical challenges associated with these thermal processes. This review presents the status of these technologies in the wastewater industry including an in‐depth discussion of system configuration and operating characteristics and fate of emerging contaminants.