New Water‐Soluble Au(III) Complexes with Xyloside‐Based Ligands: Synthesis, Structural Characterization, Solution Studies and Catalytic Evaluation. Issue 9 (19th January 2023) - Pascual, Laura M. H.
Abstract: A short and convenient approach to the original xyloside‐based ligands, has been achieved, using d ‐xylose as a starting material. The complexation properties of these ligands towards Au(III) cations were studied by different methods, such as multinuclear NMR, mass spectrometry, elemental analysis. A preliminary study using protometric titrations has been carried out in aqueous solution under various pH conditions, thus in order to investigate the binding of Au(III) cations to these ligands. Furthermore, molecular calculations were performed to obtain additional structural information. The catalytic activity of the most stable Au(III) complexes was evaluated for the homogeneous reduction of 4‐nitrophenol (4‐NP) to 4‐aminophenol (4‐AP) in the presence of NaBH4 . Abstract : Herein, we have chosen to demonstrate the potential of d ‐xylose, one of the most abundant sugars in the lignocellulosic biomass, as a platform molecule to prepare new xyloside‐based ligands and to study the complexation properties of these ligands towards Au 3+ cations in water. Their catalytic activity was evaluated for the reduction of 4‐nitrophenol (4‐NP) to 4‐aminophenol (4‐AP) with NaBH4 .