Fast Response and Visual Transparency Switching Hydrochromic Film Based on the Rational Structure of Cellulose/Poloxamer Copolymers Design for Smart Window. Issue 6 (6th January 2023)

• Record Type: Journal Article
• Authors: Guo, Yuqian; An, Xianhui; Qian, Xueren
• Is Part Of: Macromolecular rapid communications. Volume 44:Issue 6(2023)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2023-01-06
• Subjects: bioinspired designs -- fast responses -- hydrochromic films -- light scattering -- visual transparency switching; Macromolecules -- Periodicals; Polymers -- Periodicals; Chemistry -- Periodicals; 547.705
• DOI: 10.1002/marc.202200831
• Languages: English
• ISSNs: 1022-1336

Abstract

Abstract: The authors are motivated to develop a series of hydrochromic copolymers with fast response, reversibility, repeatability, and visual transparency transition. The hydrochromic block copolymers are based on the rational ratio of hydrophilic segments of poloxamer block and hydrophobic segments of ethyl cellulose according to the preparation method of polyurethane. By tuning the ratio of hydrophilic segments or adding hygroscopic salts, the hydrochromic polymer is endowed with the ability to visualize the transparency in response to the relative humidity. Especially, the response time of the polymer is extremely shortened, up to 1 s for the optimized sample. Within the moisture stimulation, the hygroscopic swelling increases the film thickness, leading to a reversible transparency switching from a highly transparent state (82%) to an opaque white state (20.5%). Abstract : Bioinspired hydrochromic film with fast response (1 s), reversibility, repeatability, and visual transparency transition based on the rational ratio of hydrophilic segments and hydrophobic segments is prepared. Within the moisture stimulation, the hygroscopic swelling increases the film thickness, leading to a reversible transparency switching from a highly transparent state (82%) to an opaque white state (20.5%).