A Catalytic Copper/Cobalt Oxide Interface for Efficient Hydrogen Generation. Issue 2 (4th March 2022)

• Record Type: Journal Article
• Authors: Xu, Wenjing; Zhang, Sheli; Shen, Ruofan; Peng, Zhikun; Liu, Baozhong; Li, Jun; Zhang, Zhanying; Li, Baojun
• Is Part Of: Energy & environmental materials. Volume 6:Issue 2(2023)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2022-03-04
• Subjects: ammonia borane -- metal -- metal oxide -- metal‐organic framework -- synergistic effect; Power resources -- Environmental aspects -- Periodicals; Renewable energy sources -- Periodicals; Environmental engineering -- Periodicals; 333.79
• DOI: 10.1002/eem2.12279
• Languages: English
• ISSNs: 2575-0356

Abstract

Abstract : Metal nanoparticles and metal oxides promisingly provide different catalytic active sites at their interfaces. Constructing high‐density interfaces is essential to maximize synergies. Herein, a Cu–Co3 O4 nanoparticles interfacial structure produced via pyrolysis and moderate oxidation from metal‐organic frameworks has been designed to boost the intrinsic activity. The Cu–Co3 O4 nanoparticles composites exhibit a turnover frequency of 57.5 min −1 for ammonia borane hydrolysis, far higher than those of monometallic Cu and Co3 O4 nanoparticles, showing the synergistic effect of Cu and Co3 O4 nanoparticles at their interface. Density functional theory calculations and in situ Raman spectroscopy reveal the catalytic mechanism of dual active sites, in which Co3 O4 nanoparticles at Cu–Co3 O4 interface efficiently bind and activate water molecules and Cu nanoparticles easily activate NH3 BH3 molecules. This study opens up a new pathway for achieving high‐efficiency noble metal‐free catalysts for hydrogen generation and other heterogeneous catalysis. Abstract : The Cu–Co3 O4 nanoparticles (NPs) interfacial composite with a turnover frequency of 57.5 min −1 for the hydrolysis of ammonia borane shows the synergistic effect of Cu and Co3 O4 NPs. This study opens up a new pathway for achieving high‐efficiency noble metal‐free catalysts for hydrogen generation and other heterogeneous catalyses.