A Turn‐On Chromogenic and Fluorogenic 2‐Aminobenzophenyl‐Isoniazid Sensor for Selective Detection of Cu2+ Ions in Water Samples and Vegetables. Issue 10 (7th March 2023)

• Record Type: Journal Article
• Authors: Christopher Leslee, Denzil Britto; Madheswaran, Bharathi; Gunasekaran, Jayapratha; Karuppannan, Sekar; Bharathi Kuppannan, Shanmuga
• Is Part Of: ChemistrySelect. Volume 8:Issue 10(2023)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2023-03-07
• Subjects: Fluorescence -- Intramolecular Charge Transfer -- Isonazid -- Ligand-Metal Charge Transfer -- Turn-ON; Chemistry -- Periodicals; 540.5
• DOI: 10.1002/slct.202203406
• Languages: English
• ISSNs: 2365-6549

Abstract

Abstract: A novel 2‐aminobenzophenyl‐isonazid (BPNH) was developed for Turn‐On green emissive sensor for Cu 2+ ions. The probe is highly selective to Cu 2+ ions in presence of interfering heavy metals. The presence of acid hydrazide and amine group facilitate the strong interaction of the probe with Cu 2+ ion. The optical spectral investigation of the probe (E)‐N′‐((2‐aminophenyl)(phenyl)methylene)isonicotinohydrazide (BPNH) with Cu 2+ ions showed Intramolecular Charge Transfer (ICT) process and Ligand‐Metal Charge transfer (LMCT) are responsible for fluorescence Turn‐On emission. The ensemble BPNH+Cu 2+ is reversible with addition of S 2− ions. The sensor BPNH displayed a lowest detection limit, DL=8.32×10 −7 M (nanomolar). The real sample analysis application of the ligand BPNH for Cu 2+ quantification has been demonstrated with water samples collected from various sources and vegetable extracts. Abstract : A novel 2‐aminobenzophenyl‐isoniazid (BPNH) was developed for Turn‐On green emissive sensor for Cu 2+ ions. The ensemble BPNH+Cu 2+ is reversible with addition of S 2− ions. An ICT triggered Turn‐ON sensor. The sensor BPNH displayed a lowest detection limit, DL=8.32×10 −7 M (nanomolar). The real sample analysis application of Cu 2+ quantification in water samples and vegetables was demonstrated.