Rücktitelbild: Bor‐Zentrierte Lewis‐Supersäuren durch Redoxaktive Liganden: Anwendung in der C‐F‐ und S‐F‐Bindungsaktivierung (Angew. Chem. 13/2023). (6th March 2023)

• Record Type: Journal Article
• Authors: Köring, Laura; Stepen, Arne; Birenheide, Bernhard; Barth, Simon; Leskov, Maxim; Schoch, Roland; Krämer, Felix; Breher, Frank; Paradies, Jan
• Is Part Of: Angewandte Chemie. Volume 135:Number 13(2023)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2023-03-06
• Subjects: C-F-Bindungsaktivierung -- Ferrocen -- Fluor -- Lewis-Supersäuren -- S-F-Bindungsaktivierung; Chemistry -- Periodicals; 540
• DOI: 10.1002/ange.202301632
• Languages: English
• ISSNs: 0044-8249

Abstract

Abstract : One‐electron oxidation converts the ferrocene‐substituted borane into a Lewis superacid, as reported by Frank Breher, Jan Paradies, and co‐workers in their Communication (e202216959) . The Lewis superacid activates almost inert carbon–fluorine and sulfur–fluorine bonds for reductions, alkylations, and arylations to form new chemical bonds.